Faculty of Education

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An ionicity diagram for the family of [{Ru ₂(CF ₃CO ₂) ₄} ₂(TCNQR _x)] (TCNQR _x = R-substituted 7,7,8,8-tetracyano-p-quinodimethane)

Keita Nakabayashi; Masaki Nishio; Keiko Kubo; Wataru Kosaka; Hitoshi Miyasaka (Profiled Authors: HITOSHI MIYASAKA; WATARU KOUSAKA)

Dalton Transactions. 2012;41(20):6072-6074.

A diagram of energies between the HOMO of donor (D) and LUMO of acceptor (A) vs. ΔE 1/2(DA) (= E 1/2(D) - E 1/2(A): E 1/2 = first-redox potential) clearly demonstrates the ionicity in the series of D/A assemblies, [{Ru 2(CF 3CO 2) 4} 2(TCNQR x)]·n(solv) (TCNQR x = 2,5- or 2,3,5,6-R-substituted 7,7,8,8-tetracyano-p- quinodimethane; R x = H 4, F 2, Cl 2, Br 2, F 4, Me 2, (OMe) 2). © 2012 The Royal Society of Chemistry.

PMID: 22495318    

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