Scopus Publication Detail
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EPR-ENDOR characterization of ( 17O, 1H, 2H) water in manganese catalase and its relevance to the oxygen-evolving complex of photosystem II
Iain L. McConnell; Vladimir M. Grigoryants; Charles P. Scholes; William K. Myers; Ping-Yu Chen; James W. Whittaker; Gary W. Brudvig(Profiled Author: James Whittaker)
Journal of the American Chemical Society. 2012;134(3):1504-1512.Abstract
The synthesis of efficient water-oxidation catalysts demands insight into the only known, naturally occurring water-oxidation catalyst, the oxygen-evolving complex (OEC) of photosystem II (PSII). Understanding the water oxidation mechanism requires knowledge of where and when substrate water binds to the OEC. Mn catalase in its Mn(III)-Mn(IV) state is a protein model of the OEC's S
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