Scopus Publication Detail
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Zhenqing Shi; James T. Nurmi; Paul G. Tratnyek(Profiled Author: Paul Tratnyek)
Environmental Science and Technology. 2011;45(4):1586-1592.Abstract
Oxidation-reduction potential (ORP) measurements have been widely used to assess the results of injection of nano zerovalent iron (nZVI) for groundwater remediation, but the significance of these measurements has never been established. Using rotating disk electrodes (RDE) in suspensions of nZVI, we found the electrode response to be highly complex but also a very sensitive probe for a range of fundamentally significant processes. The time dependence of the electrode response reflects both a primary effect (attachment of nZVI onto the electrode surface) and several secondary effects (esp., oxidation of iron and variations in dissolved H
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