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Paul Tratnyek Institute of Environmental Health

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Paul Tratnyek

Research Interest Keywords

contaminants, degradation, kinetics, mechanisms, redox, reduction, oxidation, dechlorination, water, treatment, purification, disinfection

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(503) 494-6999

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http://www.ebs.ogi.edu/tratnyek/

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The publication detail shows the title, authors (with indicators showing other profiled authors), information on the publishing organization, abstract and a link to the article in Scopus. This abstract is what is used to create the fingerprint of the publication.


Recovery of iron/iron oxide nanoparticles from solution: Comparison of methods and their effects

James T. Nurmi; Vaishnavi Sarathy; Paul G. Tratnyek; Donald R. Baer; James E. Amonette; Abhi Karkamkar

(Profiled Authors: James Nurmi; Paul Tratnyek)

Journal of Nanoparticle Research. 2011;13(5):1937-1952.

Abstract

Most methods currently being used to recover Fe0-core/oxide-shell nanoparticles from solutions (including the solvents they are synthesized or stored in) are potentially problematic because they may alter the particle composition (e.g., depositing salts formed from solutes) or leave the particles prone to transformations during subsequent storage and handling (e.g., due to residual moisture). In this study, several methods for recovery of nanoparticles from aqueous solution were studied to determine how they affect the structure and reactivity of the recovered materials. Simple washing of the nanoparticles during vacuum filtration (i.e., "flash drying") can leave up to ∼17 wt% residual moisture. Modeling calculations suggest this moisture is mostly capillary or matric water held between particles and particle aggregates, which can be removed by drying for short periods at relative vapor pressures below 0.9. Flash drying followed by vacuum drying, all under N2, leaves no detectable residue from precipitation of solutes (detectable by X-ray photoelectron spectroscopy, XPS), no significant changes in overall particle composition or structure (determined by transmission electron microscopy, TEM), and negligible residual moisture (by thermogravimetric analysis, TGA). While this improved flash-drying protocol may be the preferred method for recovering nanoparticles for many purposes, we found that Feo-core/oxide-shell nanoparticles still exhibit gradual aging during storage when characterized electrochemically with voltammetry. © Springer Science+Business Media B.V. 2010.

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