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Pierre Moenne-Loccoz Institute of Environmental Health

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Carboxylate as the protonation site in (peroxo)diiron(III) model complexes of soluble methane monooxygenase and related diiron proteins

Loi H. Do; Takahiro Hayashi; Pierre Moënne-Loccoz; Stephen J. Lippard

(Profiled Author: Pierre Moenne-Loccoz)

Journal of the American Chemical Society. 2010;132(4):1273-1275.

Abstract

(Chemical Equation Presented) Addition of H+ to a synthetic (μ-1,2-peroxo)diiron(III) model complex results in protonation of a carboxylate rather than the peroxo ligand. This conclusion is based on spectroscopic evidence from UV-vis, 57Fe Mössbauer, resonance Raman, infrared, and 1H/19F NMR studies. These results suggest a similar role for protons in the dioxygen activation reactions in soluble methane monooxygenase and related carboxylate-bridged diiron enzymes. Copyright © 2010 Chemical Society.


PMID: 20055391     PMCID: PMC2812653    

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