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Vibrational analysis of mononitrosyl complexes in hemerythrin and flavodiiron proteins: Relevance to detoxifying no reductase
Takahiro Hayashi; Jonathan D. Caranto; Hirotoshi Matsumura; Donald M. Kurtz; Pierre Moënne-Loccoz(Profiled Author: Pierre Moenne-Loccoz)
Journal of the American Chemical Society. 2012;134(15):6878-6884.Abstract
Flavodiiron proteins (FDPs) play important roles in the microbial nitrosative stress response in low-oxygen environments by reductively scavenging nitric oxide (NO). Recently, we showed that FMN-free diferrous FDP from Thermotoga maritima exposed to 1 equiv NO forms a stable diiron-mononitrosyl complex (deflavo-FDP(NO)) that can react further with NO to form N
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